Manuscript communicated/ under preparation (Updated on January, 2024)

6. Sanhati et al. ʺLight irradiated 2+2 cycloaddition reactionsʺ Manuscript under preparation

5. Devendra et al. ʺEnantioselective C-H Bond Functionalization/Annulation of Ferroceneʺ Manuscript under preparation

4. Svastik et al. ʺLigand assisted Metal selenoether complexes for electrocatalytic hydrogen evolution reactionʺ Manuscript under preparation

3. Saket et al. ʺSynthesis & Application of Organotellurium cationsʺ Manuscript under preparation

2. Raushan et al. ʺLight Driven C-C Coupling Reactionʺ work in progress

1. Raviraj et al. ʺEnantioselective C-H Functionalization of Ferroceneʺ Manuscript under preparation

63. Sattar, M.; Shareef, M.; Patidar, K.; Kumar, S. ʺCopper-Catalyzed 8-Aminoquinoline Assisted Aryl Chalcogenation of Ferroceneamide with Aryl Disulfides, Diselenides, and Ditelluridesʺ, J. Org. Chem. 2018, 83, 8241-8249; DOI: 10.1021/acs.joc.8b00974

64. Rathore, V.; Upadhyay, A.; Kumar, S. ʺA Organodiselenide with Dual Mimic Function of Sulfhydryl Oxidases and Glutathione Peroxidases: Aerial Oxidation of Organothiols to Organodisulfidesʺ, Org. Lett. 2018, 20, 6274-6278; DOI: 10.1021/acs.orglett.8b02756

61. Bhandary, S.; Sirohiwal, A.; Kadu, R.; Kumar, S.; Chopra, D. ʺDispersion Stabilized Se/Te...π Double Chalcogen Bonding Synthons in in Situ Cryocrystallized Divalent Organochalcogen Liquidsʺ Cryst. Growth Des. 2018, 18, 3734-3739; DOI: 10.1021/acs.cgd.8b00585

62. Shukla, R.; Claiser, N.; Souhassou, M.; Lecomte, C.; Balkrishna, S. J.; Kumar, S.; Chopra, D. ʺExploring the simultaneous σ-hole/π-hole bonding characteristics of a Br...π interaction in an ebselen derivative via experimental and theoretical electron-density analysisʺ International Union of Crystallography (IUCr), 2018, 5, 647-653; DOI: https://doi.org/10.1107/S2052252518011041

Publications

65. Kadu, R.; Batabyal, M.; Kadyan, H.; Koner, A. L.; Kumar, S. ʺAn efficient copper-catalyzed synthesis of symmetrical bis(N-arylbenzamide) selenides and their conversion to hypervalent spirodiazaselenuranes and hydroxy congenersʺ, Dalton Trans. 2019, 48, 7249-7260; DOI: 10.1039/c8dt04832k

66. Rathore, V.; Kumar, S. ʺVisible-light-induced metal and reagent-free oxidative coupling of sp2 C-H bonds with organo-dichalcogenides: synthesis of 3-organochalcogenyl indolesʺ, Green Chem. 2019, 21, 2670-2676; Advance Article. DOI:10.1039/C9GC00007K

67. Rathore, V.; Jose, C.; Kumar, S. ʺOrganoselenium Small Molecules as Catalysts for Oxidative Functionalization of Organic Moleculesʺ, Invited Review, New J. Chem. 2019, 43, 8852-8864;  DOI:10.1039/C9NJ00964G

68. Jana, S.; Verma, A.; Rathore, V.; Kumar, S. ʺ Synthesis of Novel C₂-Symmetric Sulfur Based Catalyst: Asymmetric Bromo/Seleno Functionalized Normal and Medium-Sized Ringsʺ, Synlett 2019, 30, 1667-1672; DOI: ST-2019-02-w0086-C

69. Sattar, M.; Patidar, K.; Thorat, R. A.; Kumar, S. ʺCopper Mediated Selective Mono and Sequential Organochalcogenation of C-H Bond: Synthesis of Hybrid Unsymmetrical Aryl Ferrocene Chalcogenidesʺ, J. Org. Chem. 2019, 84, 11, 6669-6678; DOI: 10.1021/acs.joc.9b00311

71. Verma, A.; Banjara, L. S.; Meena, R.; Kumar, S. ʺTransition-Metal-Free Synthesis of N-Substituted Phenanthridinones and Spiro-isoindolinones: C(sp²)-N and C(sp²)-O Coupling through Radical Pathwayʺ Asian J. Org. Chem. 2020, 9, 105-110; DOI: 10.1002/ajoc.201900704

70. Sattar, M.; Kumar, N.; Yadav, P.; Mandhar, Y.; Kumar, S. ʺ8-Aminoquinoline-Assisted Synthesis and Crystal Structure Studies of Ferrocenyl Aryl Sulfonesʺ Chem. Asian J. 2019, 14, 4807-4813; DOI: 10.1002/asia.201901334

72. Upadhyay, A.; Batabyal, M.; Kanika; Kumar, S. ʺOrganoseleniums: Generated and Exploited in Oxidative Reactionsʺ Chem. Lett. 2020, 49, 395-408; DOI: 10.1246/cl.200015

73. Thorat, R. A.; Jain, S.; Sattar, M.; Yadav, P.; Mandhar, Y.; Kumar, S. ʺSynthesis of Chiral substituted 2-Aryl-Ferrocenes by the Catellani Reactionʺ, J. Org. Chem. 2020, 85, 14866-14878; DOI: 10.1021/acs.joc.0c01360

74. Upadhyay, A.; Bhakuni, B. S.; Meena, R.; Kumar, S. ʺRadical Chain Breaking Bis(ortho-organoselenium) Substituted Phenolic Antioxidantsʺ Chem Asian J. 2021, 16, 966-973; DOI: 10.1002/asia.202100139

75. Upadhyay, A.; Jha, R. K.; Batabyal, M.; Dutta, T.; Koner, A. L.; Kumar, S. ʺJanus-Faced Oxidant and Antioxidant Profiles of Organo Diselenides ʺ Dalton Trans. 2021, 50, 14576-14594; DOI: 10.1039/D1DT01565F (HOT Article)

77. Upadhyay, A.; Saurav, K. V.; Varghese, E. L.; Hodage, A. S.; Paul, A.; Awasthi, M. K.; Singh, S. K.; Kumar, S. ʺProton reduction by a bimetallic zinc selenolate electrocatalystʺ RSC Adv. 2022, 12, 3801-3808; DOI: 10.1039/d1ra08614f

76. Thorat, R. A..; Jain, S.; Parganiha, D.; Kumar, S. ʺPd-Catalysed Benzylic C-H Functionalizationʺ; Book Chapter in ʺHandbook of CH-Functionalization (CHF)ʺ Willey-VCH GmbH, Weinhein, 2022, ISBN: 9783527834242

78. Upadhyay, A.; Meena, H.; Jha, R. K.; Kanika; Kumar, S. ʺIsolation of Monomeric Copper(II) Phenolate Selenoether Complexes using Chelating ortho-Bisphenylselenide-phenolate Ligands and Their Electrocatalytic Hydrogen Gas Evolution Activityʺ Dalton Trans. 2022, 51, 7284-7293; DOI: 10.1039/D2DT00678B

79. Batabyal, M.; Upadhyay, A.; Kadu, R.; Birudukota, N. C.; Chopra, D.; Kumar, S. ʺTetravalent Spiroselenurane Catalysts: Intramolecular Se...N Chalcogen Bond Driven Catalytic Disproportionation of H₂O₂ to H₂O and O₂ and Activation of I₂ and NBSʺ, Inorg. Chem. 2022, 61, 23, 8729-8745; DOI: 10.1021/acs.inorgchem.2c00651, Accepted for Front Cover

80. Batabyal, M.; jain, S.; Upadhyay, A.; Raju, S.; Kumar, S. ʺA base-free copper-assisted synthesis of C₂-symmetric spirotelluranes and biaryls based on divergent stoichiometry of Na₂Teʺ, Chem. Commun. 2022, 58, 7050-7053; DOI: 10.1039/D2CC02181A

81. Raju, S.; Singh, H. B.; Kumar, S. ʺHybrid Quinoline Telluroether Ligand Derived Copper and Silver Complexes: Synthesis, Structural and Electronic Propertiesʺ, Eur. J. Inorg. Chem. 2022, e202200300; DOI: 10.1002/ejic.202200300

82. Jha, R. K.; Upadhyay, A.; Kanika; Jain, S.; K A, Neena; Kumar, S. ʺLight-Driven Carbon-Carbon Coupling of α-sp³-CH of Aliphatic Alcohols with sp²-CH Bond of 1,4-Naphthoquinonesʺ, Org. Lett. 2022, 24, 41, 7605-7610; DOI: 10.1021/acs.orglett.2c03066

Sangit Research Group

Department of Chemistry IISER Bhopal

Publications

 

 

83. Upadhyay, A.; Kanika; Mandhar, Y.; Batabyal, M.; Raju, S.; Jaiswal, S.; Butcher, R. J.; Kumar, S. ʺSynthesis of Cobalt(II) Phenolate Selenoether Complexes to Mimic Hydrogenase-like Activity for Hydrogen Gas Productionʺ, Dalton Trans. 2023, 52, 159-174; DOI: 10.1039/D2DT02820D

84. Thorat, R. A.; Mandhar, Y.; Parganiha, D.; Patil, K. B.; Singh, V.; Shakir, B.; Raju, S.; Kumar, S. ʺA Planar-Chiral Palladium Complex Derived from a Weak Oxygen Donor N,N-Diisopropyl Ferrocenecarboxamide Ligandʺ, ChemistrySelect 2023, e202203945; DOI: 10.1002/slct.202203945

85. Sahoo, P.; lenka, D. R.; Batabyal, M.; Pain, P. K.; Kumar, S.; Manna, D.; Kumar, A. ʺDetailed Insights into the Inhibitory Mechanism of New Ebselen Derivatives against Main Protease (M^pro) of Severe Acute Respiratory Syndrome Coronavirus-2 (SARS-CoV-2)ʺ, ACS Pharmacol. Transl. Sci. 2023, 6, 171-180; DOI: 10.1021/acsptsci.2c00203

86. Jha, R. K.; Batabyal, M.; Kumar, S. ʺBlue Light Irradiated Metal-, Oxidant-, and Base-Free Cross-Dehydrogenative Coupling of C(sp²)-H and N-H Bonds: Amination of Naphthoquinones with Aminesʺ, J. Org. Chem. 2023, 88, 11, 7401-7424 (Most Read/Downloaded Article of the month May and June, 2023); DOI: 10.1021/acs.joc.3c00666

88. Jain, S.; Batabyal, M.; Thorat, R. A.; Choudhary, P.; Jha, R. K.; Kumar, S. ʺ2-Benzamide Tellurenyl Iodides: Synthesis and Their Catalytic Role in CO₂ Mitigationʺ, Chem. Eur. J. 2023, 29, e202301502; DOI: 10.1002/chem.202301502

87. Raju, S.; Singh, H. B.; Kumar, S.; Butcher, R. J. ʺThe Coordination Behavior of the Tellurium Incorporated Mercuraazametallamacrocycle and Investigation of d¹⁰∙∙∙d¹⁰ Interactions between Closed Shell (Ag⁺ Hg²⁺) Metal Ionsʺ, Chem. Eur. J. 2023, 29, e202301322; DOI: 10.1002/chem.202301322

89. Jain, S.; Satpute, S. S.; Jha, R. K.; Patel, M.; Kumar, S. ʺBidentate Ligand Driven Intramolecularly Te...O Bonded Organotellurium Cations from Synthesis, Stability to Catalysisʺ, Chem. Eur. J. 2023, e202303089; DOI: 10.1002/chem.202303089

90. Jha, R. K.; Rohilla, K.; Jain, S.; Parganiha, D.; Kumar, S. ʺBlue-Light Irradiated Mn(0)-Catalyzed Hydroxylation and C(sp³)-H Functionalization of Unactivated Alkanes with C(sp²)-H Bonds of Quinones for Alkylated Hydroxy Quinones and Parvaquoneʺ, Chem. Eur. J. 2024, e202303537; DOI: 10.1002/chem.202303537

91. Batabyal, M.; Jaiswal, S.; Jha, R. K.; Kumar, S. ʺDirecting Group Strategy for the Isolation of Organoselenium(VI) Benzoselenonates: Metal-Free Catalysts for Hydrogen Evolution Reactionʺ, J. Am. Chem. Soc. 2024, 146, 57-61; DOI: 10.1021/jacs.3c10572 (This work is highlighted in Spotlights on Recent JACS Publications, Volume 146, Issue 1)